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Safety
/ MSDS |
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Autochem-Rhino
> Hints / Tips |
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 Hints
& Tips |
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SECTION ONE - IDENTIFICATION |
| MANUFACTURER’S
NAME :- |
Chemical
Specialties Ltd. |
| |
Street Address: - 116 Princes Street,
Onehunga, Auckland. |
| |
P.O.Box 29-109,
Greenwoods Corner, Auckland. |
| |
Phone / Fax (09) 636 8618. |
| |
Emergency Contact in
case of poisoning:-New Zealand :- National Poisons Centre
Ph (03) 474 7000 , Australia :- Poisons Information Centre
Phone 13 1126 |
| |
Trade Name: -
Rhino Filler |
| |
Shipping Name:- Polyester Resin
Kit. |
| U.N. Number: -3269 |
HAZCHEM 3(Y) |
| Dangerous Goods Class: -3.3 |
Packing Group 111 |
| Australian Emergency
Procedure Guide 3A1 |
Marine Pollutant |
This product
is comprised of two components :- (A) A filler paste
based on unsaturated polyester resin in styrene and
(B) A benzoyl peroxide based initiator.
Hazard and Safety aspects are identified separately
under (A) or (B) where necessary. |
|
|
SECTION TWO- HAZARDOUS
COMPONENTS |
Component
|
CAS
No |
Proportion |
Threshold
Limit Value |
(A) Styrene |
100-42-5 |
14-18% |
50 ppm |
(B) Benzoyl Peroxide |
94-36-0 |
50% |
- |
(B)Alkyl Benzoate |
131298-44-7 |
19% |
-
|
|
SECTION THREE - PHYSICAL
DATA |
| (A) Appearance:
Buff coloured paste. |
| Odour: Sweet
or sharp aromatic odour of styrene. |
| Boiling Point (Styrene) :
145ºC |
Percent Volatiles : 14-18 |
| Specific Gravity : 0.7-0.9
|
Water Miscibility : Immiscible |
| (B) Appearance:
Red paste. |
|
| Odour:
Slight ester odour . |
|
| Specific Gravity
: 1.2 |
Water Miscibility : Immiscible |
|
SECTION FOUR - FIRE
AND EXPLOSION HAZARD |
| (A)Flammable
Vapour |
| Flammable
Limits: - |
LEL 1.1% |
| |
UEL 6.1% |
|
| Flash Point:
- (Styrene) 31ºC (Setaflash) |
| (B) Flash Point N/A |
Flammable Limits:- N/A |
| EXTINGUISHING MEDIA.
Foam, carbon dioxide, dry powder, water fog. |
UNUSUAL FIRE
AND EXPLOSION HAZARDS.
(A) Styrene will polymerise at elevated temperatures.
If this occurs in a closed container there is risk of
violent rupture.
(B) Fire hazard increases if allowed to dry. Oxygen for
combustion partly supplied by the peroxide itself.
|
SPECIAL FIREFIGHTING
PROCEDURES.
None. |
|
SECTION
FIVE - HEALTH HAZARD DATA |
| LD 50 Oral Rat > 5000mg / kg for both
components of this Polyester Resin Kit. |
| EMERGENCY FIRST AID PROCEDURES.
|
(A)
Ingestion : Do not induce vomiting. Aspiration of material
into the lungs could cause pneumonitis which can be fatal.
Give milk or water. Seek medical attention.
(B) Ingestion : Seek medical attention.
If more than 15 minutes from a hospital induce vomiting
preferably using ipecac syrup APF. Otherwise do not induce
vomiting, give sips of water preferably with charcoal tablets.
Take affected person to hospital
|
| Inhalation of Vapour: Move victim
to fresh air. Apply artificial respiration or give oxygen
if necessary. |
| Eye Contact: Flush
with copious amounts of water - lift eyelids repeatedly. Seek
medical attention. |
| Skin Contact: Wash thoroughly
with soap and water. Remove contaminated clothing and launder
before re-use. |
| Advice to Doctor:
Treat symptomatically. |
|
SECTION SIX - REACTIVITY
DATA |
|
| CONDITIONS TO AVOID
: Exposure to sunlight, open flames, contamination, prolonged
storage above 27°C. |
| HAZARDOUS POLYMERISATION:
May occur |
| MATERIALS TO AVOID:
Strong acids, peroxides, other oxidising agents. |
| CONDITIONS
TO AVOID:Elevated temperatures, improper contact with
peroxides or other contaminants. |
|
| CONDITIONS TO AVOID
: exposure to sunlight, open flames,elevated temperatures
and drying conditions. |
| MATERIALS TO AVOID:
Reducing agents, promotors eg. dimethyl aniline, cobalt naphthenate,
hot materials. |
|
SECTION
SEVEN - SPILL OR LEAK PROCEDURES |
Steps to be taken if the
material is released or spilled.
Eliminate all sources of ignition (flames, hot surfaces,
electrical, static or frictional sparks). Ventilate area.
Prevent contamination of storm-water drains.
Use plastic or other non-sparking tools to scrape up spilled
material and place in a suitable container for use or disposal. |
| Waste
disposal method. Portions (A) & (B) may be mixed
together and allowed to gel before disposal as solid waste
in accordance with appropriate regulations. |
|
| SECTION
EIGHT - SPECIAL PROTECTION INFORMATION |
| Respiratory protection. Use with
adequate ventilation. If necessary use canister mask (organic
vapour filter ) or approved air-line mask. |
| Ventilation. General
dilution or local exhaust to maintain vapour concentration
below TLV. |
| Protective Gloves. PVC type. |
| Eye Protection. Safety spectacles. |
| Other Protective Equipment. Normal work
clothing giving arm and leg cover. |
|
SECTION NINE - SPECIAL
PRECAUTIONS |
Precautions to be taken
in handling and storage.
When handling keep away from heat and sources of ignition.
Avoid contact with skin and eyes. Use only in well ventilated
areas.
Store in a dry well ventilated space in original containers
(ideally below 27°C to prevent spoilage ). Open containers
slowly in case of internal pressure. |
|
|
|
|
MSDS
Autochem Panel Cream
|
SECTION ONE - IDENTIFICATION |
| MANUFACTURER’S
NAME :- |
Chemical
Specialties Ltd. |
| |
Street Address: - 116 Princes Street,
Onehunga, Auckland. |
| |
P.O.Box 29-109,
Greenwoods Corner, Auckland. |
| |
Phone / Fax (09) 636 8618. |
| |
Emergency Contact in
case of poisoning:-New Zealand :- National Poisons Centre
Ph (03) 474 7000 , Australia :- Poisons Information Centre
Phone 13 1126 |
| |
Trade Name: -
Autochem Panel Cream |
| |
Shipping Name:- Polyester Resin
Kit. |
| U.N. Number: -3269 |
HAZCHEM 3(Y) |
| Dangerous Goods Class: -3.3 |
Packing Group 111 |
| Australian Emergency
Procedure Guide 3A1 |
Marine Pollutant |
This product
is comprised of two components :- (A) A filler paste
based on unsaturated polyester resin in styrene and
(B) A benzoyl peroxide based initiator.
Hazard and Safety aspects are identified separately
under (A) or (B) where necessary. |
|
|
SECTION TWO- HAZARDOUS
COMPONENTS |
Component
|
CAS
No |
Proportion |
Threshold
Limit Value |
(A) Styrene |
100-42-5 |
14-18% |
50 ppm |
(B) Benzoyl Peroxide |
94-36-0 |
50% |
- |
(B)Alkyl Benzoate |
131298-44-7 |
19% |
-
|
|
SECTION THREE - PHYSICAL
DATA |
| (A) Appearance:
Buff coloured paste. |
| Odour: Sweet
or sharp aromatic odour of styrene. |
| Boiling Point (Styrene) :
145ºC |
Percent Volatiles : 14-18 |
| Specific Gravity : 0.7-0.9
|
Water Miscibility : Immiscible |
| (B) Appearance:
Red paste. |
|
| Odour:
Slight ester odour . |
|
| Specific Gravity
: 1.2 |
Water Miscibility : Immiscible |
|
SECTION FOUR - FIRE
AND EXPLOSION HAZARD |
| (A)Flammable
Vapour |
| Flammable
Limits: - |
LEL 1.1% |
| |
UEL 6.1% |
|
| Flash Point:
- (Styrene) 31ºC (Setaflash) |
| (B) Flash Point N/A |
Flammable Limits:- N/A |
| EXTINGUISHING MEDIA.
Foam, carbon dioxide, dry powder, water fog. |
UNUSUAL FIRE
AND EXPLOSION HAZARDS.
(A) Styrene will polymerise at elevated temperatures.
If this occurs in a closed container there is risk of
violent rupture.
(B) Fire hazard increases if allowed to dry. Oxygen for
combustion partly supplied by the peroxide itself.
|
SPECIAL FIREFIGHTING
PROCEDURES.
None. |
|
SECTION
FIVE - HEALTH HAZARD DATA |
| LD 50 Oral Rat > 5000mg / kg for both
components of this Polyester Resin Kit. |
| EMERGENCY FIRST AID PROCEDURES.
|
(A)
Ingestion : Do not induce vomiting. Aspiration of material
into the lungs could cause pneumonitis which can be fatal.
Give milk or water. Seek medical attention.
(B) Ingestion : Seek medical attention.
If more than 15 minutes from a hospital induce vomiting
preferably using ipecac syrup APF. Otherwise do not induce
vomiting, give sips of water preferably with charcoal tablets.
Take affected person to hospital
|
| Inhalation of Vapour: Move victim
to fresh air. Apply artificial respiration or give oxygen
if necessary. |
| Eye Contact: Flush
with copious amounts of water - lift eyelids repeatedly. Seek
medical attention. |
| Skin Contact: Wash thoroughly
with soap and water. Remove contaminated clothing and launder
before re-use. |
| Advice to Doctor:
Treat symptomatically. |
|
SECTION SIX - REACTIVITY
DATA |
|
| CONDITIONS TO AVOID
: Exposure to sunlight, open flames, contamination, prolonged
storage above 27°C. |
| HAZARDOUS POLYMERISATION:
May occur |
| MATERIALS TO AVOID:
Strong acids, peroxides, other oxidising agents. |
| CONDITIONS
TO AVOID:Elevated temperatures, improper contact with
peroxides or other contaminants. |
|
| CONDITIONS TO AVOID
: exposure to sunlight, open flames,elevated temperatures
and drying conditions. |
| MATERIALS TO AVOID:
Reducing agents, promotors eg. dimethyl aniline, cobalt naphthenate,
hot materials. |
|
SECTION
SEVEN - SPILL OR LEAK PROCEDURES |
Steps to be taken if the
material is released or spilled.
Eliminate all sources of ignition (flames, hot surfaces,
electrical, static or frictional sparks). Ventilate area.
Prevent contamination of storm-water drains.
Use plastic or other non-sparking tools to scrape up spilled
material and place in a suitable container for use or disposal. |
| Waste
disposal method. Portions (A) & (B) may be mixed
together and allowed to gel before disposal as solid waste
in accordance with appropriate regulations. |
|
| SECTION
EIGHT - SPECIAL PROTECTION INFORMATION |
| Respiratory protection. Use with
adequate ventilation. If necessary use canister mask (organic
vapour filter ) or approved air-line mask. |
| Ventilation. General
dilution or local exhaust to maintain vapour concentration
below TLV. |
| Protective Gloves. PVC type. |
| Eye Protection. Safety spectacles. |
| Other Protective Equipment. Normal work
clothing giving arm and leg cover. |
|
SECTION NINE - SPECIAL
PRECAUTIONS |
Precautions to be taken
in handling and storage.
When handling keep away from heat and sources of ignition.
Avoid contact with skin and eyes. Use only in well ventilated
areas.
Store in a dry well ventilated space in original containers
(ideally below 27°C to prevent spoilage ). Open containers
slowly in case of internal pressure. |
|
|
|
|
MSDS
Autochem Panel Filler
|
SECTION ONE - IDENTIFICATION |
| MANUFACTURER’S
NAME :- |
Chemical
Specialties Ltd. |
| |
Street Address: - 116 Princes Street,
Onehunga, Auckland. |
| |
P.O.Box 29-109,
Greenwoods Corner, Auckland. |
| |
Phone / Fax (09) 636 8618. |
| |
Emergency Contact in
case of poisoning:-New Zealand :- National Poisons Centre
Ph (03) 474 7000 , Australia :- Poisons Information Centre
Phone 13 1126 |
| |
Trade Name: -
Autochem Panel Filler |
| |
Shipping Name:- Polyester Resin
Kit. |
| U.N. Number: -3269 |
HAZCHEM 3(Y) |
| Dangerous Goods Class: -3.3 |
Packing Group 111 |
| Australian Emergency
Procedure Guide 3A1 |
Marine Pollutant |
This product
is comprised of two components :- (A) A filler paste
based on unsaturated polyester resin in styrene and
(B) A benzoyl peroxide based initiator.
Hazard and Safety aspects are identified separately
under (A) or (B) where necessary. |
|
|
SECTION TWO- HAZARDOUS
COMPONENTS |
Component
|
CAS
No |
Proportion |
Threshold
Limit Value |
(A) Styrene |
100-42-5 |
14-18% |
50 ppm |
(B) Benzoyl Peroxide |
94-36-0 |
50% |
- |
(B)Alkyl Benzoate |
131298-44-7 |
19% |
-
|
|
SECTION THREE - PHYSICAL
DATA |
| (A) Appearance:
Buff coloured paste. |
| Odour: Sweet
or sharp aromatic odour of styrene. |
| Boiling Point (Styrene) :
145ºC |
Percent Volatiles : 14-18 |
| Specific Gravity : 0.7-0.9
|
Water Miscibility : Immiscible |
| (B) Appearance:
Red paste. |
|
| Odour:
Slight ester odour . |
|
| Specific Gravity
: 1.2 |
Water Miscibility : Immiscible |
|
SECTION FOUR - FIRE
AND EXPLOSION HAZARD |
| (A)Flammable
Vapour |
| Flammable
Limits: - |
LEL 1.1% |
| |
UEL 6.1% |
|
| Flash Point:
- (Styrene) 31ºC (Setaflash) |
| (B) Flash Point N/A |
Flammable Limits:- N/A |
| EXTINGUISHING MEDIA.
Foam, carbon dioxide, dry powder, water fog. |
UNUSUAL FIRE
AND EXPLOSION HAZARDS.
(A) Styrene will polymerise at elevated temperatures.
If this occurs in a closed container there is risk of
violent rupture.
(B) Fire hazard increases if allowed to dry. Oxygen for
combustion partly supplied by the peroxide itself.
|
SPECIAL FIREFIGHTING
PROCEDURES.
None. |
|
SECTION
FIVE - HEALTH HAZARD DATA |
| LD 50 Oral Rat > 5000mg / kg for both
components of this Polyester Resin Kit. |
| EMERGENCY FIRST AID PROCEDURES.
|
(A)
Ingestion : Do not induce vomiting. Aspiration of material
into the lungs could cause pneumonitis which can be fatal.
Give milk or water. Seek medical attention.
(B) Ingestion : Seek medical attention.
If more than 15 minutes from a hospital induce vomiting
preferably using ipecac syrup APF. Otherwise do not induce
vomiting, give sips of water preferably with charcoal tablets.
Take affected person to hospital
|
| Inhalation of Vapour: Move victim
to fresh air. Apply artificial respiration or give oxygen
if necessary. |
| Eye Contact: Flush
with copious amounts of water - lift eyelids repeatedly. Seek
medical attention. |
| Skin Contact: Wash thoroughly
with soap and water. Remove contaminated clothing and launder
before re-use. |
| Advice to Doctor:
Treat symptomatically. |
|
SECTION SIX - REACTIVITY
DATA |
|
| CONDITIONS TO AVOID
: Exposure to sunlight, open flames, contamination, prolonged
storage above 27°C. |
| HAZARDOUS POLYMERISATION:
May occur |
| MATERIALS TO AVOID:
Strong acids, peroxides, other oxidising agents. |
| CONDITIONS
TO AVOID:Elevated temperatures, improper contact with
peroxides or other contaminants. |
|
| CONDITIONS TO AVOID
: exposure to sunlight, open flames,elevated temperatures
and drying conditions. |
| MATERIALS TO AVOID:
Reducing agents, promotors eg. dimethyl aniline, cobalt naphthenate,
hot materials. |
|
SECTION
SEVEN - SPILL OR LEAK PROCEDURES |
Steps to be taken if the
material is released or spilled.
Eliminate all sources of ignition (flames, hot surfaces,
electrical, static or frictional sparks). Ventilate area.
Prevent contamination of storm-water drains.
Use plastic or other non-sparking tools to scrape up spilled
material and place in a suitable container for use or disposal. |
| Waste
disposal method. Portions (A) & (B) may be mixed
together and allowed to gel before disposal as solid waste
in accordance with appropriate regulations. |
|
| SECTION
EIGHT - SPECIAL PROTECTION INFORMATION |
| Respiratory protection. Use with
adequate ventilation. If necessary use canister mask (organic
vapour filter ) or approved air-line mask. |
| Ventilation. General
dilution or local exhaust to maintain vapour concentration
below TLV. |
| Protective Gloves. PVC type. |
| Eye Protection. Safety spectacles. |
| Other Protective Equipment. Normal work
clothing giving arm and leg cover. |
|
SECTION NINE - SPECIAL
PRECAUTIONS |
Precautions to be taken
in handling and storage.
When handling keep away from heat and sources of ignition.
Avoid contact with skin and eyes. Use only in well ventilated
areas.
Store in a dry well ventilated space in original containers
(ideally below 27°C to prevent spoilage ). Open containers
slowly in case of internal pressure. |
|
|
|
| |
|
|
|
Autochem-Rhino
A Division Of Chemical Specialties Ltd
116 Princes St. Onehunga. P.O.Box, 29109 Greenwoods Cnr, Auckland, New
Zealand.
Phone 0064 9 636 8618. Fax 0064 9 636 8618. E Mail rhino@chemspec.co.nz |
