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 Health
& Safety |
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Synthepol MSDSs
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Valspar MSDSs
(Adobe pdf files)
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MSDS
Synthepol Unsaturated Polyester Resin Solution |
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SECTION
ONE - IDENTIFICATION |
|
| MANUFACTURER’S
NAME :- |
SYNTHEPOL
(a division of Chemical Specialties Ltd.) |
| |
Street Address: - 116 Princes Street,
Onehunga, Auckland. |
| |
P.O.Box 29-109,
Greenwoods Corner, Auckland. |
| |
Phone / Fax (09) 636 8618. |
| |
Emergency Contact in
case of poisoning:- National Poisons Centre Ph (03) 474
7000 |
| |
Trade Name: - Synthepol
. |
| |
Chemical Name:- Unsaturated
Polyester Resin Solution |
| U.N. Number: - 1866 |
HAZCHEM 3(Y) |
| Dangerous Goods Class: - 3.B |
Packing Group 111 |
| |
Marine Pollutant |
Manufacturers
Product Codes
This Material Safety Data Sheet covers all grades
of Synthepol polyester resins and flowcoats, which
carry the reference MSDS Code GP in technical literature. |
|
|
| |
SECTION
TWO- HAZARDOUS COMPONENTS |
|
Component
|
CAS
No |
Proportion |
Threshold
Limit Value |
Styrene |
100-42-5 |
20-55% |
50 ppm |
|
| |
SECTION
THREE - PHYSICAL DATA |
|
| Appearance:
Clear, cloudy or coloured viscous liquid. |
| Odour:
Sweet or sharp aromatic odour of styrene. |
| Boiling Point (Styrene) :
145°C |
Percent Volatiles : 20-55 |
| Specific Gravity
: 1.1-1.7 |
Water Miscibility : Immiscible. |
|
| |
SECTION
FOUR - FIRE AND EXPLOSION HAZARD |
|
| Flammable Liquid. |
| Flammable
Limits: - |
LEL 1.1% |
| |
UEL 6.1% |
|
| Flash Point:
- 31°C (Setaflash) |
| EXTINGUISHING MEDIA.
Foam, carbon dioxide, dry powder, water fog. |
UNUSUAL FIRE
AND EXPLOSION HAZARDS.
Styrene will polymerise at elevated temperatures. If this
occurs in a closed container there is risk of violent rupture. |
SPECIAL FIREFIGHTING
PROCEDURES.
None. Fight like a fuel-oil fire. |
|
| |
SECTION
FIVE - HEALTH HAZARD DATA |
|
| THRESHOLD LIMIT VALUES. Styrene 50ppm. |
EFFECTS
OF OVER EXPOSURE.
Inhalation of vapour can cause headache, nausea, intoxication
and irritation of the respiratory tract. |
| EMERGENCY FIRST AID PROCEDURES.
|
| Ingestion: Do not
induce vomiting. Aspiration of material into the lungs could
cause pneumonitis, which can be fatal. Give milk or water.
Seek medical attention. |
| Inhalation of Vapour: Move victim
to fresh air. Apply artificial respiration or give oxygen
if necessary. |
| Eye Contact: Flush
with copious amounts of water - lift eyelids repeatedly. Seek
medical attention. |
| Skin Contact: Wash thoroughly
with soap and water. Remove contaminated clothing and launder
before re-use. |
| Advice to Doctor:
Treat symptomatically. |
|
| |
SECTION
SIX - REACTIVITY DATA |
|
STABILITY
|
Unstable X |
| |
Stable |
|
| CONDITIONS TO AVOID
: Exposure to sunlight, open flames, contamination and
prolonged storage above 27°C. |
| MATERIALS TO AVOID: Strong acids,
peroxides, other oxidising agents. |
HAZARDOUS POLYMERISATION
:
|
May occur X |
| |
Will not occur. |
|
| CONDITIONS TO AVOID:Elevated temperatures,
improper contact with peroxides or other contaminants. |
|
| |
SECTION
SEVEN - SPILL OR LEAK PROCEDURES |
|
Steps to be taken if the material is
released or spilled.
Eliminate all sources of ignition ( flames, hot surfaces,
electrical, static or frictional sparks) .Ventilate area.
Dyke area of spill and pump material into drums for use
or disposal. Absorb remainder on sand or perlite and place
the saturated absorbent into closed containers for disposal.
Prevent contamination of stormwater drains. |
Waste disposal method.
Destroy by liquid incineration with off-gas scrubber.
Contaminated absorbent to be deposited in secure landfill
in accordance with appropriate regulations or incinerated.
L iquid material mixed with peroxide initiators should be
allowed to gel before disposal as solid waste in accordance
with appropriate regulations. |
|
| |
SECTION
EIGHT - SPECIAL PROTECTION INFORMATION |
|
| Respiratory protection. Use with
adequate ventilation. If necessary use canister mask (organic
vapour filter ) or approved air-line mask. |
| Ventilation. General
dilution or local exhaust to maintain vapour concentration
below TLV. |
| Protective Gloves. PVC type. |
| Eye Protection.
Safety goggles or splash mask. |
| Other Protective Equipment. Normal
work clothing giving arm and leg cover. |
|
| |
SECTION
NINE - SPECIAL PRECAUTIONS |
|
Precautions to be taken
in handling and storage.
Store in a bunded area or approved flammable goods store
away from direct heat (ideally below 27°C to prevent
spoilage). Open drums slowly in case of internal pressure.
In bulk storage check vents and flame arrestors for plugging
and formation of polymer. |
| Other Precautions.
Ground (earth) all connections and containers when using
above flash point. |
|
|
|
| |
MSDS
Synthepol Wax Solution SW 16 |
|
| |
SECTION
ONE - IDENTIFICATION |
|
| MANUFACTURER’S
NAME :- |
SYNTHEPOL
(a division of Chemical Specialties Ltd.) |
| |
Street Address: - 116 Princes Street,
Onehunga, Auckland. |
| |
P.O.Box 29-109,
Greenwoods Corner, Auckland. |
| |
Phone / Fax (09) 636 8618. |
| |
Emergency Contact in
case of poisoning:- National Poisons Centre Ph (03) 474
7000 |
| |
Trade Name: - Synthepol
Wax Solution SW 16 |
| |
Shipping Name: -
Flammable Liquid n.o.s. |
| U.N. Number: - 1993 |
HAZCHEM 3(Y) |
| Dangerous Goods Class: - 3.B |
Packing Group 111 |
| Toxic Substances Schedule 4 Harmful
Substance |
Marine Pollutant |
|
|
| |
SECTION
TWO- HAZARDOUS COMPONENTS |
|
Component
|
CAS
No |
Proportion |
Threshold
Limit Value |
Styrene |
100-42-5 |
approx 48% |
50ppm |
White Spirit |
64742-82-1 |
approx
43% |
100ppm |
Toluene |
108-88-3 |
<4% |
100ppm |
|
| |
SECTION
THREE - PHYSICAL DATA |
|
| Appearance: -
Clear to hazy colourless liquid. |
| Odour:-
Sweet or sharp aromatic odour of styrene. |
| Boiling Point (Styrene) :-
145°C |
Percent Volatiles :- approx
95 |
| Specific Gravity
:- 0.75-0.85 |
Water Miscibility :- Immiscible. |
|
| |
SECTION
FOUR - FIRE AND EXPLOSION HAZARD |
|
| Flammable Liquid. |
| Flammable Limits:
- |
LEL 0.7% |
| |
UEL 6.5% |
|
| Flash Point: - 31°C (Setaflash) |
| EXTINGUISHING MEDIA. Foam,
carbon dioxide, dry powder, water fog. |
UNUSUAL FIRE AND
EXPLOSION HAZARDS.
Styrene will polymerise at elevated temperatures. If this
occurs in a closed container there is risk of violent rupture. |
SPECIAL FIREFIGHTING
PROCEDURES.
None. Fight like a fuel-oil fire. |
|
| |
SECTION
FIVE - HEALTH HAZARD DATA |
|
| THRESHOLD LIMIT VALUES. Styrene 50ppm.
Toluene 100ppm. White Spirits 100ppm |
EFFECTS OF
OVER EXPOSURE.
Inhalation of vapour can cause headache, nausea, intoxication
and irritation of the respiratory tract. |
| EMERGENCY FIRST AID PROCEDURES.
|
| Ingestion: Do not
induce vomiting. Aspiration of material into the lungs could
cause pneumonitis, which can be fatal. Give milk or water. Seek
medical attention. |
| Inhalation of Vapour: Move victim to
fresh air. Apply artificial respiration or give oxygen if necessary. |
| Eye Contact: Flush
with copious amounts of water - lift eyelids repeatedly. Seek
medical attention. |
Skin Contact: Wash thoroughly
with soap and water. Remove contaminated
c lothing and launder before re-use. |
| Advice to Doctor:
Treat symptomatically. |
|
| |
SECTION
SIX - REACTIVITY DATA |
|
STABILITY
|
Unstable X |
| |
Stable |
|
| CONDITIONS TO AVOID :
Exposure to sunlight, open flames, contamination and prolonged
storage above 27°C. |
| MATERIALS TO AVOID: Strong acids, peroxides,
other oxidising agents. |
HAZARDOUS POLYMERISATION
:
|
May occur X |
| |
Will not occur. |
|
| CONDITIONS TO AVOID:Elevated temperatures,
improper contact with peroxides or other contaminants. |
|
| |
SECTION
SEVEN - SPILL OR LEAK PROCEDURES |
|
Steps to be taken if the material is released
or spilled.
Eliminate all sources of ignition ( flames, hot surfaces,
electrical, static or frictional sparks) .Ventilate area.
Dyke area of spill and pump material into drums for use or
disposal. Absorb remainder on sand or perlite and place the
saturated absorbent into closed containers for disposal. Prevent
contamination of stormwater drains. |
Waste disposal method.
Destroy by liquid incineration with off-gas scrubber.
Contaminated absorbent to be deposited in secure landfill
in accordance with appropriate regulations or incinerated. |
|
| |
SECTION
EIGHT - SPECIAL PROTECTION INFORMATION |
|
| Respiratory protection. Use with adequate
ventilation. If necessary use canister mask (organic vapour
filter ) or approved air-line mask. |
| Ventilation. General
dilution or local exhaust to maintain vapour concentration
below TLV. |
| Protective Gloves. PVC type. |
| Eye Protection.
Safety goggles or splash mask. |
| Other Protective Equipment. Normal
work clothing giving arm and leg cover. |
|
| |
SECTION
NINE - SPECIAL PRECAUTIONS |
|
Precautions to be taken in handling and
storage.
Store in a bunded area or approved flammable goods store away
from direct heat (ideally below 27°C to prevent spoilage).
Open drums slowly in case of internal pressure. In bulk storage
check vents and flame arrestors for plugging and formation
of polymer. |
| Other Precautions.
Ground (earth) all connections and containers when using above
flash point. |
|
|
| |
|
| |
|
|
|
|
| |
SECTION
ONE - IDENTIFICATION |
|
| MANUFACTURER’S
NAME :- |
SYNTHEPOL
(a division of Chemical Specialties Ltd.) |
| |
Street Address: - 116 Princes Street,
Onehunga, Auckland. |
| |
P.O.Box 29-109,
Greenwoods Corner, Auckland. |
| |
Phone / Fax (09) 636 8618. |
| |
Emergency Contact in
case of poisoning:- National Poisons Centre Ph (03) 474
7000 |
| |
Trade Name: - Synthepol
Plyprime |
| |
Shipping Name: -
Flammable Liquid n.o.s. |
| U.N. Number: - 1993 |
HAZCHEM 3(Y) |
| Dangerous Goods Class: - 3.B |
Packing Group 111 |
| |
Marine Pollutant |
|
|
| |
SECTION
TWO- HAZARDOUS COMPONENTS |
|
Component
|
CAS
No |
Proportion |
Threshold
Limit Value |
Styrene |
100-42-5 |
>95% |
50 ppm |
Metal Octoates or Naphthenates
|
- |
<5% |
- |
|
| |
SECTION
THREE - PHYSICAL DATA |
|
| Appearance: -
Clear, deep red / purple liquid. |
| Odour:-
Sweet or sharp aromatic odour of styrene. |
| Boiling Point (Styrene) :-
145°C |
Percent Volatiles :- >95 |
| Specific Gravity
:- 0.85-0.95 |
Water Miscibility :-Immiscible. |
|
| |
SECTION
FOUR - FIRE AND EXPLOSION HAZARD |
|
| Flammable Liquid. |
| Flammable Limits:
- |
LEL 1.1% |
| |
UEL 6.1% |
|
| Flash Point: - 31°C (Setaflash) |
| EXTINGUISHING MEDIA. Foam,
carbon dioxide, dry powder, water fog. |
UNUSUAL FIRE AND
EXPLOSION HAZARDS.
Styrene will polymerise at elevated temperatures. If this
occurs in a closed container there is risk of violent rupture. |
SPECIAL FIREFIGHTING
PROCEDURES.
None. Fight like a fuel-oil fire. |
|
| |
SECTION
FIVE - HEALTH HAZARD DATA |
|
| THRESHOLD LIMIT VALUES. Styrene 50ppm. |
EFFECTS OF
OVER EXPOSURE.
Inhalation of vapour can cause headache, nausea, intoxication
and irritation of the respiratory tract. |
| EMERGENCY FIRST AID PROCEDURES.
|
| Ingestion: Do not
induce vomiting. Aspiration of material into the lungs could
cause pneumonitis, which can be fatal. Give milk or water. Seek
medical attention. |
| Inhalation of Vapour: Move victim to
fresh air. Apply artificial respiration or give oxygen if necessary. |
| Eye Contact: Flush
with copious amounts of water - lift eyelids repeatedly. Seek
medical attention. |
| Skin Contact: Wash thoroughly
with soap and water. Remove contaminated clothing and launder
before re-use. |
| Advice to Doctor:
Treat symptomatically. |
|
| |
SECTION
SIX - REACTIVITY DATA |
|
STABILITY
|
Unstable X |
| |
Stable |
|
| CONDITIONS TO AVOID :
Exposure to sunlight, open flames, contamination and prolonged
storage above 27°C. |
| MATERIALS TO AVOID: Strong acids, peroxides,
other oxidising agents. |
HAZARDOUS POLYMERISATION
:
|
May occur X |
| |
Will not occur. |
|
| CONDITIONS TO AVOID:Elevated temperatures,
improper contact with peroxides or other contaminants. |
|
| |
SECTION
SEVEN - SPILL OR LEAK PROCEDURES |
|
Steps to be taken if the material is released
or spilled.
Eliminate all sources of ignition (flames, hot surfaces, electrical,
static or frictional sparks). Ventilate area. Dyke area of
spill and pump material into drums for use or disposal. Absorb
remainder on sand or perlite and place the saturated absorbent
into closed containers for disposal. Prevent contamination
of stormwater drains. |
Waste disposal
method. Destroy by liquid incineration with off-gas scrubber.
Contaminated absorbent to be deposited in secure landfill
in accordance with appropriate regulations or incinerated. |
|
| |
SECTION
EIGHT - SPECIAL PROTECTION INFORMATION |
|
| Respiratory protection. Use with adequate
ventilation. If necessary use canister mask (organic vapour
filter) or approved air-line mask. |
| Ventilation. General
dilution or local exhaust to maintain vapour concentration
below TLV. |
| Protective Gloves. PVC type. |
| Eye Protection.
Safety goggles or splash mask. |
| Other Protective Equipment. Normal
work clothing giving arm and leg cover. |
|
| |
SECTION
NINE - SPECIAL PRECAUTIONS |
|
Precautions to be taken in handling and
storage.
Store in a bunded area or approved flammable goods store away
from direct heat (ideally below 27°C to prevent spoilage).
Open drums slowly in case of internal pressure. In bulk storage
check vents and flame arrestors for plugging and formation
of polymer. |
| Other Precautions.
Ground (earth) all connections and containers when using above
flash point. |
|
|
| |
|
|
|
Synthepol
A Division Of Chemical Specialties Ltd
116 Princes St. Onehunga. P.O.Box, 29109 Greenwoods Cnr, Auckland, New
Zealand.
Phone 0064 9 636 8618. Fax 0064 9 636 8618. E Mail synthepol@chemspec.co.nz |
